LXXXIII.—Mercury acetamide

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N-(2-Chloro­phenyl­sulfon­yl)acetamide

The asymmetric unit of the title compound, C(8)H(8)ClNO(3)S, contains two independent mol-ecules in which the C-S-N-C torsion angles are -71.7 (3) and 61.2 (3)°. The benzene rings and the SO(2)-NH-CO-C segments form dihedral angles of 80.2 (1) and 88.1 (2)° in the two independent mol-ecules. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains in the b-axis direc...

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N-(4-Isopropoxyphen­yl)acetamide

In the mol-ecule of the title compound, C(11)H(15)NO(2), the planar acetamide unit [maximum deviation of 0.0014 (6) Å] is oriented at a dihedral angle of 19.68 (4)° with respect to the aromatic ring. An intra-molecular C-H⋯O inter-action results in the formation of a six-membered ring. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis.

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In the mol-ecular structure of the title compound, C(9)H(11)NO(3)S, the N-H and C=O bonds are anti to each other, while the amide H atom is syn with respect to the ortho-methyl group in the benzene ring. The C-S-N-C torsion angle is -58.2 (2)°, indicating a twist in the mol-ecule. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains along the c axis.

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ژورنال

عنوان ژورنال: J. Chem. Soc., Trans.

سال: 1898

ISSN: 0368-1645

DOI: 10.1039/ct8987300783